Application of geochemical characterization, multivariate statistics and geological modelling in assessment and prediction studies on selected coal and gold mine waste in South Africa
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Date
2023
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Publisher
University of the Western Cape
Abstract
Over the years, South Africa has generated vast amounts of coal fly ash and gold slime tailings, constituting over 70% of the country's waste materials. These byproducts contain elevated levels of trace metals, posing a potential threat to the environment upon release. Addressing this issue requires a comparative study of the environmental impact of coal fly ash and selected mine tailings on water resources and land pollution. This research aims to investigate and compare leachability, metal release, oxidation effects, and environmental pollution between coal fly ash and gold tailings. By contrasting these aspects, the study seeks to enhance understanding of the potential risks associated with these materials, aiding informed decision-making for their management and regulation. Additionally, the research explores the correlation between gold tailings' acid potential generation and coal fly ash's alkaline potential generation in terms of leachability, metal release, oxidation effects, and environmental pollution. The research employed comprehensive laboratory experiments and analytical investigations, including leaching tests under simulated weathering conditions. A total of 51 gold tailings samples and 66 coal fly ash samples were analysed through SEM and XRD for mineralogical insights and ICP-MS and XRF for geochemical analyses. Statistical analysis revealed the significant roles of pH, Fe ions, Ca2+, and Mg2+ in metal extraction from both materials. Notably, the study identified key factors contributing to the environmental impact of coal fly ash and gold tailings. SEM imagery highlighted heterogeneous characteristics in gold tailings, while factor analysis indicated the potential release of ferrous ionic species, contributing to acidity. Trace elements like Ni, Zn, Pb, and Cu were predominantly associated with Fe/Mn oxides during leaching experiments, facilitating their mobilization with acid-generating ions.
Description
Philosophiae Doctor - PhD
Keywords
South Africa, Gold mine, Geochemical characterization, Geology, Coal fly ash