Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,Nā]palladium(II) acetonitrile monosolvate
| dc.contributor.author | Motswainyana, William M. | |
| dc.contributor.author | Onani, Martin O. | |
| dc.contributor.author | Jacobs, Jeroen | |
| dc.contributor.author | van Meervelt, Luc | |
| dc.date.accessioned | 2013-10-13T20:11:22Z | |
| dc.date.available | 2013-10-13T20:11:22Z | |
| dc.date.issued | 2012 | |
| dc.description.abstract | The title complex, [PdCl2(C20H20N2)] CH3CN, was synthesized by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline with dichlorido(cycloocta-1,5-diene)palladium(II) in dry CH2Cl2. The PdII ion is coordinated by two N atoms of the bidentate quinoline ligand and by two chloride anions, generating a distorted square-planar coordination geometry around the metal centre. There is a detectable trans influence for the chloride ligands. The crystal packing is characterized by ā stacking between the quinoline rings. The use of acetonitrile as the crystallization solvent was essential for obtaining good-quality crystals. | en_US |
| dc.description.accreditation | Web of Science | en_US |
| dc.identifier.citation | Motswainyana, W.M., et al. (2012). Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,Nā]palladium(II) acetonitrile monosolvate. Acta Cryst. C68, m356ām358 | en_US |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.uri | http://hdl.handle.net/10566/751 | |
| dc.language.iso | en | en_US |
| dc.privacy.showsubmitter | false | |
| dc.publisher | International Union of Crystallography | en_US |
| dc.rights | Copyright International Union of Crystallography. This file may be freely used for educational purposes, as long as it is not altered in any way. Acknowledgement of the authors and the source is required. | |
| dc.source.uri | http://dx.doi.org/10.1107/S0108270112045970 | |
| dc.status.ispeerreviewed | true | |
| dc.title | Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,Nā]palladium(II) acetonitrile monosolvate | en_US |
| dc.type | Article | en_US |
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