Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,Nā]palladium(II) acetonitrile monosolvate
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Date
2012
Journal Title
Journal ISSN
Volume Title
Publisher
International Union of Crystallography
Abstract
The title complex, [PdCl2(C20H20N2)] CH3CN, was synthesized
by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline
with dichlorido(cycloocta-1,5-diene)palladium(II) in dry
CH2Cl2. The PdII ion is coordinated by two N atoms of the
bidentate quinoline ligand and by two chloride anions,
generating a distorted square-planar coordination geometry
around the metal centre. There is a detectable trans influence
for the chloride ligands. The crystal packing is characterized
by ā stacking between the quinoline rings. The use of
acetonitrile as the crystallization solvent was essential for
obtaining good-quality crystals.
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Citation
Motswainyana, W.M., et al. (2012). Dichlorido-[2-(2,6-diethylphenyl)iminomethylquinoline-N,Nā]palladium(II) acetonitrile monosolvate. Acta Cryst. C68, m356ām358