Effect of the structure of Ni nanoparticles on the electrocatalytic activity of Ni@Pd/C for formic acid oxidation

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dc.contributor.authorWang, Rongfang
dc.contributor.authorWang, Hui
dc.contributor.authorWang, Xingli
dc.contributor.authorLiao, Shijun
dc.contributor.authorLinkov, Vladimir
dc.contributor.authorJi, Shan
dc.date.accessioned2018-02-16T09:35:16Z
dc.date.available2018-02-16T09:35:16Z
dc.date.issued2013
dc.description.abstractNi@Pd/C catalysts were synthesized, using Ni/C with different crystalline structures prepared with various ligands. A series of characterizations were performed by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy. The results indicated the electrocatalysts with amorphous/crystalline (denoted as Nia and Nic) Ni structures decorated with Pd. The formic acid electrocatalytic oxidation results showed that the peak current of Nia@Pd/C was about 1.2 times higher than that of Nic@Pd/C. The good electrochemical performance and stability of Pd-modified amorphous Ni substrate reveals that the core structure plays an important role in the electrocatalytic activity and the change of the structure can improve the activity and stability of electrocatalysts.en_US
dc.description.accreditationWeb of Science
dc.identifier.citationWang, R. et al. (2013). Effect of the structure of Ni nanoparticles on the electrocatalytic activity of Ni@Pd/C for formic acid oxidation. International Journal of Hydrogen Energy, 38(29): 13125 – 13131en_US
dc.identifier.issn0360-3199
dc.identifier.urihttp://dx.doi.org/10.1016/j.ijhydene.2013.01.104
dc.identifier.urihttp://hdl.handle.net/10566/3507
dc.language.isoenen_US
dc.privacy.showsubmitterFALSE
dc.publisherElsevieren_US
dc.rightsThis is the author-version of the article published online at: http://dx.doi.org/10.1016/j.ijhydene.2013.01.104
dc.status.ispeerreviewedTRUE
dc.subjectAmorphousen_US
dc.subjectElectrocatalystsen_US
dc.subjectFuel cellsen_US
dc.subjectFormic acid oxidationen_US
dc.subjectCoreeshell structureen_US
dc.titleEffect of the structure of Ni nanoparticles on the electrocatalytic activity of Ni@Pd/C for formic acid oxidationen_US
dc.typeArticleen_US

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