Coal fly ash and acid mine drainage based heterogeneous Fe catalysts Friedel-Crafts alkylation reaction
| dc.contributor.advisor | Petrik, Leslie | |
| dc.contributor.author | Hlatywayo, Tapiwa | |
| dc.date.accessioned | 2020-08-06T08:46:49Z | |
| dc.date.accessioned | 2024-05-13T12:40:51Z | |
| dc.date.available | 2021-08-30T22:10:06Z | |
| dc.date.available | 2024-05-13T12:40:51Z | |
| dc.date.issued | 2020 | |
| dc.description | Philosophiae Doctor - PhD | en_US |
| dc.description.abstract | The catalytic support materials used in the present study are zeolite HBEA and MCM-41. These high silica zeolites were synthesised from coal fly ash (CFA) waste via a novel approach that involved a fusion step, acid assisted silica extraction and removal of Al, Ca and Na from the silica by treatment with oxalic acid. The generated silica was converted to HBEA and MCM-41 via conventional hydrothermal treatment. The metal incorporation onto HBEA was done via two approaches namely; liquid phase ion exchange (LIE) and wet impregnation (WI) while the loading on MCM-41 was only done via WI since the material does not possess exchange sites. The metal solution precursors were AMD and Fe extracted from CFA (FeAsh) via acid leaching followed by pH regulation by concentrated NaOH. This is the first time these solutions were tested as possible metal precursors in catalyst synthesis. | en_US |
| dc.identifier.uri | https://hdl.handle.net/10566/14746 | |
| dc.language.iso | en | en_US |
| dc.publisher | University of Western Cape | en_US |
| dc.rights.holder | University of Western Cape | en_US |
| dc.subject | Acid leaching | en_US |
| dc.subject | Acid mine drainage | en_US |
| dc.subject | Friedel-Crafts alkylation | en_US |
| dc.subject | Coal fly ash | en_US |
| dc.title | Coal fly ash and acid mine drainage based heterogeneous Fe catalysts Friedel-Crafts alkylation reaction | en_US |