Supported 3-D Pt nanostructures: the straightforward synthesis and enhanced electrochemical performance for methanol oxidation in an acidic medium

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Date

2013

Journal Title

Journal ISSN

Volume Title

Publisher

Springer

Abstract

Noble metal nanostructures with branched morphologies [i.e., 3-D Pt nanoflowers (NFs)] by tridimensionally integrating onto conductive carbon materials are proved to be an efficient and durable electrocatalysts for methanol oxidation. The well-supported 3-D Pt NFs are readily achieved by an efficient cobalt-induced/carbon-mediated galvanic reaction approach. Due to the favorable nanostructures (3-D Pt configuration allowing a facile mass transfer) and supporting effects (including framework stabilization, spatially separate feature, and improved charge transport effects), these 3-D Pt NFs manifest much higher electrocatalytic activity and stability toward methanol oxidation than that of the commercial Pt/C and Pt-based electrocatalysts.

Description

Keywords

Nanoflowers, Branched morphologies, Supported electrocatalyst, Methanol oxidation, Fuel cells

Citation

Li, Z. et al. (2013). Supported 3-D Pt nanostructures: the straightforward synthesis and enhanced electrochemical performance for methanol oxidation in an acidic medium. Journal of Nanoparticle Research, 15: 1959