Synthesis, theoretical calculation, and biological studies of mono- and diphenyltin(iv) complexes of n-methyl-n-hydroxyethyldithiocarbamate

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dc.contributor.authorAdeyemi, Jerry O.
dc.contributor.authorOlasunkanmi, Lukman O.
dc.contributor.authorFadaka, Adewale O.
dc.date.accessioned2022-09-19T07:53:01Z
dc.date.available2022-09-19T07:53:01Z
dc.date.issued2022
dc.description.abstractIn this study, chlorophenyltin(IV) [(C6H5)(Cl)Sn(L)2] and diphenyltin(IV) [(C6H5)2Sn(L)2] of N-methyl-N-hydroxyethyldithiocarbamate were prepared and characterized using various spectroscopic methods (FTIR, 1H, 13C, and 119Sn NMR) and elemental analysis. The FTIR and NMR spectral data, used to establish the structure of the compounds, showed the formation of the complexes via coordination to the two sulfur atoms from the dithiocarbamate ligand and the respective phenyltin(IV) derivatives. This coordination mode was further explored by DFT calculations, which showed that the bonding around the Sn center in [(C6H5)2Sn(L)2] was more asymmetric compared to the bonding around [(C6H5)(Cl)Sn(L)2]. However, the Sn–S bonds in [(C6H5)(Cl)Sn(L)2] were found to be more covalent than those in [(C6H5)2Sn(L)2].en_US
dc.identifier.citationAdeyemi, J. O. et al. (2022). Synthesis, theoretical calculation, and biological studies of mono- and diphenyltin(iv) complexes of n-methyl-n-hydroxyethyldithiocarbamate. Molecules, 27(9), 2947. https://doi.org/10.3390/molecules27092947en_US
dc.identifier.issn1420-3049
dc.identifier.urihttps://doi.org/10.3390/molecules27092947
dc.identifier.urihttp://hdl.handle.net/10566/7907
dc.language.isoenen_US
dc.publisherMDPIen_US
dc.subjectOrganic chemistryen_US
dc.subjectBiotechnologyen_US
dc.subjectDithiocarbamateen_US
dc.subjectMolecularen_US
dc.titleSynthesis, theoretical calculation, and biological studies of mono- and diphenyltin(iv) complexes of n-methyl-n-hydroxyethyldithiocarbamateen_US
dc.typeArticleen_US

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