New phenylene bridged binuclear bis (imino-quinolyl) palladium(II) complexes: synthesis, characterization and Heck reactions

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dc.contributor.authorMotswainyana, William M.
dc.contributor.authorOnani, Martin O.
dc.date.accessioned2014-03-17T19:56:53Z
dc.date.available2014-03-17T19:56:53Z
dc.date.issued2012
dc.description.abstractTwo new phenylene bridged binuclear bis(imino-quinolyl) palladium (II) complexes were prepared from the reaction of the ligand 1,4-bis(imino-quinolyl)benzene, L1 with either Pd(cod)Cl2 or Pd(cod)ClMe. The molecular structure of L1 was confirmed by single crystal X-ray diffraction analysis. The structure shows two planar molecules (A and B) in the asymmetric unit. The complexes were evaluated as catalysts for Heck coupling reactions of methyl and butyl acrylate with iodobenzene, and showed high activity. The reactions proceeded at a faster initial rate and there was good selectivity for the formation of the trans- isomers.en_US
dc.description.accreditationWeb of Scienceen_US
dc.identifier.citationNew phenylene bridged binuclear bis (imino-quinolyl) palladium(II) complexes: synthesis, characterization and Heck reactions. Inorganic Chemistry Communications, 24: 221-224en_US
dc.identifier.issn1387-7003
dc.identifier.urihttp://hdl.handle.net/10566/1056
dc.language.isoenen_US
dc.privacy.showsubmitterfalse
dc.publisherElsevieren_US
dc.rightsThis is the author postprint version of an article by Elsevier. The file may be freely used, provided that acknowledgement of the source is given.
dc.source.urihttp://dx.doi.org/10.1016/j.inoche.2012.07.018
dc.status.ispeerreviewedtrue
dc.subjectBis (imino-quinolyl)en_US
dc.subjectPalladium
dc.subjectX-ray diffraction
dc.subjectHeck reactions
dc.titleNew phenylene bridged binuclear bis (imino-quinolyl) palladium(II) complexes: synthesis, characterization and Heck reactionsen_US
dc.typeArticleen_US

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