Synthesis of carbon-supported PdSn–SnO2 nanoparticles with different degrees of interfacial contact and enhanced catalytic activities for formic acid oxidation

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dc.contributor.authorWang, Hui
dc.contributor.authorLiu, Ziyue
dc.contributor.authorMa, Yanjiao
dc.contributor.authorJulian, Key
dc.contributor.authorJi, Shan
dc.contributor.authorLinkov, Vladimir
dc.contributor.authorWang, Rongfang
dc.date.accessioned2018-01-08T14:02:51Z
dc.date.available2018-01-08T14:02:51Z
dc.date.issued2013
dc.description.abstractThe conjunction of the PdSn alloy and SnO2 is of interest for improving catalytic activity in formic acid oxidation (FAO). Here, we report the synthesis of PdSn–SnO2 nanoparticles and a study of their catalytic FAO activity. Different degrees of interfacial contact between SnO2 and PdSn were obtained using two different stabilizers (sodium citrate and EDTA) during the reduction process in catalyst preparation. Compared to the PdSn alloy, PdSn–SnO2 supported on carbon black showed enhanced FAO catalytic activity due to the presence of SnO2 species. It was also found that interfacial contact between the PdSn alloy and the SnO2 phase has an impact on the activity towards CO oxidation and FAO.en_US
dc.description.accreditationWeb of Science
dc.identifier.citationWang, H. et al. (2013). Synthesis of carbon-supported PdSn-Sn02 nanoparticles with different degrees of interfacial contact and enhanced catalytic activities for formic acid oxidation. Physical Chemistry Chemical Physics, 15: 13999en_US
dc.identifier.issn1463-9076
dc.identifier.urihttp://dx.doi.org/10.1039/c3cp52101j
dc.identifier.urihttp://hdl.handle.net/10566/3364
dc.language.isoenen_US
dc.privacy.showsubmitterFALSE
dc.publisherRoyal Society of Chemistryen_US
dc.rightsThis is the author-version of the article published online at: http://dx.doi.org/10.1039/c3cp52101j
dc.subjectPdSn alloyen_US
dc.subjectSnO2en_US
dc.subjectCatalytic activityen_US
dc.subjectCO oxidationen_US
dc.subjectFAOen_US
dc.titleSynthesis of carbon-supported PdSn–SnO2 nanoparticles with different degrees of interfacial contact and enhanced catalytic activities for formic acid oxidationen_US
dc.typeArticleen_US

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