Graphol and vanadia-linkedzink-doped lithium manganese silicate nanoarchitectonic platforms for supercapatteries

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Date

2020

Journal Title

Journal ISSN

Volume Title

Publisher

University of Western cape

Abstract

Energy storage technologies are rapidly being developed due to the increased awareness of global warming and growing reliance of society on renewable energy sources. Among various electrochemical energy storage technologies, high power supercapacitors and lithium ion batteries with excellent energy density stand out in terms of their flexibility and scalability. However, supercapacitors are handicapped by low energy density and batteries lag behind in power. Supercapatteries have emerged as hybrid devices which synergize the merits of supercapacitors and batteries with the likelihood of becoming the ultimate power sources for multi-function electronic equipment and electric/hybrid vehicles in the future. But the need for new and advanced electrodes is key to enhancing the performance of supercapatteries. Leading-edge technologies in material design such as nanoarchitectonics become very relevant in this regard. This work involves the preparation of vanadium pentoxide (V2O5), pristine and zinc doped lithium manganese silicate (Li2MnSiO4) nanoarchitectures as well as their composites with hydroxylated graphene (G-ol) and carbon nanotubes (CNT).

Description

Philosophiae Doctor - PhD

Keywords

Aqueous electrolytes, Battery-supercapacitor hybrids, Carbon nanotubes, Composite nanoarchitectures, Capacitance retention, Hydroxylated graphene, Lithium manganese silicate, Mechanochemical reactions, Nanoarchitectonics, Specific capacitance, Specific energy, Specific power, Supercapatteries, Vanadia, Zinc doping

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