Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate

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dc.contributor.authorMotswainyana, William M.
dc.contributor.authorOnani, Martin O.
dc.contributor.authorJacobs, Jeroen
dc.contributor.authorvan Meervelt, Luc
dc.date.accessioned2013-10-13T20:31:28Z
dc.date.available2013-10-13T20:31:28Z
dc.date.issued2013
dc.description.abstractThe title imino–phosphine compound, [PdCl2(C26H22NP)] - CH3CN, was prepared by reaction of N-[2-(diphenylphosphanyl) benzylidene]-2-methylaniline with dichlorido(cycloocta- 1,5-diene)palladium(II) in dry CH2Cl2. The PdII cation is coordinated by the P and N atoms of the bidentate chelating ligand and by two chloride anions, generating a distorted square-planar coordination geometry. There is a detectable trans influence for the chloride ligands. The methyl group present in this structure has an influence on the crystal packing.en_US
dc.description.accreditationWeb of Scienceen_US
dc.identifier.citationMotswainyana, W.M., et al. (2013). Dichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvate. Acta Cryst. C69, 209–211en_US
dc.identifier.issn0108-2701
dc.identifier.urihttp://hdl.handle.net/10566/752
dc.language.isoenen_US
dc.privacy.showsubmitterfalse
dc.publisherInternational Union of Crystallographyen_US
dc.rightsCopyright International Union of Crystallography. This file may be freely used for educational purposes, as long as it is not altered in any way. Acknowledgement of the authors and the source is required.
dc.source.urihttp://dx.doi.org/10.1107/S0108270113002333
dc.status.ispeerreviewedtrue
dc.titleDichlorido-[(2-diphenylphosphino-benzylidene)-2-methylphenylen-amine]palladium( II) acetonitrile monosolvateen_US
dc.typeArticleen_US

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