Browsing by Author "Mohammed, Saeed"
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Item Geochemical evaluation of source rock potential and characterization of hydrocarbon occurrences in the Eastern Dahomey Basin, Nigeria(University of Western Cape, 2020) Mohammed, Saeed; Opuwari, Mimonitu; Titinchi, SalamNigeria is endowed with significant oil sand and heavy oil reserves. These reserves are found within the Cretaceous Afowo Formation in the Eastern Dahomey Basin. The petroleum systems and quality of these reserves are poorly understood. Harnessing these resources necessitate comprehensive deposit evaluation and characterization.Item Metal–metal correlation of biodegraded crude oil and associated economic crops from the Eastern Dahomey Basin, Nigeria(MDPI, 2022) Mohammed, Saeed; Opuwari, Mimonitu; Titinchi, SalamThe presence of heavy metals in plants from oil sand deposits may reflect mineralization resulting from petroleum biodegradation. Petroleum composition and heavy metal analyses were performed using thermal desorption gas chromatography and atomic absorption spectrophotometry on oil sand and plant root samples from the same localities in the Dahomey Basin. The results from the oil sand showed mainly heavy-end hydrocarbon components, humps of unresolved complex mixtures (UCM), absences of C6-C12 hydrocarbon chains, pristane, and phytane, indicating severe biodegradation. In addition, they showed varying concentrations of vanadium (2.699–7.708 ppm), nickel (4.005–11.716 ppm), chromium (1.686–5.733 ppm), cobalt (0.953–3.223 ppm), lead (0.649–0.978 ppm), and cadmium (0.188–0.461 ppm). Furthermore, these heavy metals were present in Citrus, Theobroma Cacao, Elaeis guineensis, and Cola.Item Source rock evaluation of Afowo clay type from the Eastern Dahomey Basin, Nigeria: Insights from different measurements(Springer Nature, 2020) Mohammed, Saeed; Opuwari, Mimonitu; Titinchi, SalamThe Cretaceous Afowo Formation in the Eastern Dohamey Basin is characterized by an admixture of lithofacies ranging from sandstones, claystones, shales, clays, sand/shale, and sand/clay intercalations. The sandy facies, a mix of sandstone, clay, shale, and intercalations, contain biodegraded hydrocarbons while the shales and claystones that underlie it are rich in organic matter. The hydrocarbon-bearing interval is commonly referred to as the oil sand or tar sand. In this study, Afowo clay type underlying an outcrop of the oil sand was appraised for its hydrocarbon potential with loss on ignition, thermogravimetry, and rock evaluation pyrolysis.