Efficient removal of mercury Ions stabilized by gold solution using chitosan–guar gum polymer blend in basic media

Abstract

The highly efficient removal of mercury metal ions at a higher pH (basic media) is barely reported in the literature. In this study, we developed a novel adsorbent by blending chitosan with guar gum, designed to effectively remove mercury ions from basic media by stabilizing them with a gold (Au3⁺) solution. The FTIR confirmed the compatibility of chitosan and guar gum through hydrogen bonding. The morphology of the blend exhibited an amorphous and porous structure. A mesoporous structure with a surface area, volume, and diameter of 11.843 (m2/g), 0.184 (cm2/g), and 17.072 nm, respectively, was confirmed by BET. The adsorption behavior was analyzed using isotherms and kinetics models, which best fitted with the pseudo-second-order kinetic model and Freundlich adsorption isotherm model, respectively. The adsorbent was shown to be an excellent candidate for the removal of mercury ions in water, with an adsorption efficiency of 92% at pH 12 in 60 min and a maximum adsorption capacity of 370.37 (mg/g).