Square, LynndleFourie, Lionel Fabian2024-03-192024-05-142024-03-192024-05-142023https://hdl.handle.net/10566/14995Philosophiae Doctor - PhDThis work explores using polymeric materials for space radiation shielding in low-earth orbit. Shielding against radiation is essential on any space mission. Low atomic number materials, such as hydrogen, have shown to be effective in shielding ionising radiation. However, compared to metallic alloys, these materials suer from relatively low mechanical and thermal properties, which limit their application. Aluminium (Al) enjoyed wide use in space applications as a structural and radiation shielding material. However, weight and secondary radiation generation issues have made its use as a shielding material less viable on modern space missions where cost and safety play a crucial role in planning these missions. On modern space missions, conventional shielding materials include Al alloys, high-density polyethylene, and water. The disadvantages include low thermal properties, high atomic numbers, and complex maintenance systems. This lead to exploring other materials that can mitigate some of these drawbacks. A proposed approach to replacing high atomic number metals is deploying hydrogen-rich polymers enhanced with nanofiller materials to form polymer nanocomposites. Poly-mers enhanced with nanofillers can achieve improved physical properties while pro-viding adequate radiation shielding functions at a lower weight with less secondary radiation generation.enPoly(2, 5)benzimidazole (ABPBI)Carbon Nanotubes (CNT)Polymer NanocompositesProton Radiation ShieldingLow Earth Orbit (LEO)ThesisUniversity of the Western Cape